LOTRIČ, Andrej ;SEKAVČNIK, Mihael ;KUNZE, Christian ;SPLIETHOFF, Hartmut . Simulation of Water-Gas Shift Membrane Reactor for Integrated Gasification Combined Cycle Plant with CO2 Capture. Strojniški vestnik - Journal of Mechanical Engineering, [S.l.], v. 57, n.12, p. 911-926, june 2018. ISSN 0039-2480. Available at: <https://www.sv-jme.eu/article/simulation-of-water-gas-shift-membrane-reactor-for-integrated-gasification-combined-cycle-plant-with-co2-capture/>. Date accessed: 07 oct. 2024. doi:http://dx.doi.org/10.5545/sv-jme.2011.100.
Lotrič, A., Sekavčnik, M., Kunze, C., & Spliethoff, H. (2011). Simulation of Water-Gas Shift Membrane Reactor for Integrated Gasification Combined Cycle Plant with CO2 Capture. Strojniški vestnik - Journal of Mechanical Engineering, 57(12), 911-926. doi:http://dx.doi.org/10.5545/sv-jme.2011.100
@article{sv-jmesv-jme.2011.100, author = {Andrej Lotrič and Mihael Sekavčnik and Christian Kunze and Hartmut Spliethoff}, title = {Simulation of Water-Gas Shift Membrane Reactor for Integrated Gasification Combined Cycle Plant with CO2 Capture}, journal = {Strojniški vestnik - Journal of Mechanical Engineering}, volume = {57}, number = {12}, year = {2011}, keywords = {IGCC; water-gas shift reaction; membrane reactor}, abstract = {The effectiveness of energy conversion and carbon dioxide sequestration in Integrated Gasification Combined Cycle (IGCC) is highly dependent on the syngas composition and its further processing. Water gas shift membrane reactor (WGSMR) enables a promising way of syngas-to-hydrogen conversion with favourable carbon dioxide sequestration capabilities. This paper deals with a numerical approach to the modelling of a water gas shift reaction (WGSR) in a membrane reactor which promotes a reaction process by selectively removing hydrogen from the reaction zone through the membrane, making the reaction equilibrium shifting to the product side. Modelling of the WGSR kinetics was based on Bradford mechanism which was used to develop a code within Mathematica programming language to simulate the chemical reactions. The results were implemented as initial and boundary conditions for the tubular WGSMR model designed with Aspen Plus software to analyze the broader system behaviour. On the basis of selected boundary conditions the designed base case model predicts that 89.1% CO conversion can be achieved. Calculations show that more than 70% of carbon monoxide conversion into hydrogen appears along the first 40% of reactor length scale. For isothermal conditions more than two thirds of the heat released by WGSR should be extracted from the first 20% of the reactor length. Sensitivity analysis of the WGSMR was also performed by changing the membrane’s permeance and surface area.}, issn = {0039-2480}, pages = {911-926}, doi = {10.5545/sv-jme.2011.100}, url = {https://www.sv-jme.eu/article/simulation-of-water-gas-shift-membrane-reactor-for-integrated-gasification-combined-cycle-plant-with-co2-capture/} }
Lotrič, A.,Sekavčnik, M.,Kunze, C.,Spliethoff, H. 2011 June 57. Simulation of Water-Gas Shift Membrane Reactor for Integrated Gasification Combined Cycle Plant with CO2 Capture. Strojniški vestnik - Journal of Mechanical Engineering. [Online] 57:12
%A Lotrič, Andrej %A Sekavčnik, Mihael %A Kunze, Christian %A Spliethoff, Hartmut %D 2011 %T Simulation of Water-Gas Shift Membrane Reactor for Integrated Gasification Combined Cycle Plant with CO2 Capture %B 2011 %9 IGCC; water-gas shift reaction; membrane reactor %! Simulation of Water-Gas Shift Membrane Reactor for Integrated Gasification Combined Cycle Plant with CO2 Capture %K IGCC; water-gas shift reaction; membrane reactor %X The effectiveness of energy conversion and carbon dioxide sequestration in Integrated Gasification Combined Cycle (IGCC) is highly dependent on the syngas composition and its further processing. Water gas shift membrane reactor (WGSMR) enables a promising way of syngas-to-hydrogen conversion with favourable carbon dioxide sequestration capabilities. This paper deals with a numerical approach to the modelling of a water gas shift reaction (WGSR) in a membrane reactor which promotes a reaction process by selectively removing hydrogen from the reaction zone through the membrane, making the reaction equilibrium shifting to the product side. Modelling of the WGSR kinetics was based on Bradford mechanism which was used to develop a code within Mathematica programming language to simulate the chemical reactions. The results were implemented as initial and boundary conditions for the tubular WGSMR model designed with Aspen Plus software to analyze the broader system behaviour. On the basis of selected boundary conditions the designed base case model predicts that 89.1% CO conversion can be achieved. Calculations show that more than 70% of carbon monoxide conversion into hydrogen appears along the first 40% of reactor length scale. For isothermal conditions more than two thirds of the heat released by WGSR should be extracted from the first 20% of the reactor length. Sensitivity analysis of the WGSMR was also performed by changing the membrane’s permeance and surface area. %U https://www.sv-jme.eu/article/simulation-of-water-gas-shift-membrane-reactor-for-integrated-gasification-combined-cycle-plant-with-co2-capture/ %0 Journal Article %R 10.5545/sv-jme.2011.100 %& 911 %P 16 %J Strojniški vestnik - Journal of Mechanical Engineering %V 57 %N 12 %@ 0039-2480 %8 2018-06-29 %7 2018-06-29
Lotrič, Andrej, Mihael Sekavčnik, Christian Kunze, & Hartmut Spliethoff. "Simulation of Water-Gas Shift Membrane Reactor for Integrated Gasification Combined Cycle Plant with CO2 Capture." Strojniški vestnik - Journal of Mechanical Engineering [Online], 57.12 (2011): 911-926. Web. 07 Oct. 2024
TY - JOUR AU - Lotrič, Andrej AU - Sekavčnik, Mihael AU - Kunze, Christian AU - Spliethoff, Hartmut PY - 2011 TI - Simulation of Water-Gas Shift Membrane Reactor for Integrated Gasification Combined Cycle Plant with CO2 Capture JF - Strojniški vestnik - Journal of Mechanical Engineering DO - 10.5545/sv-jme.2011.100 KW - IGCC; water-gas shift reaction; membrane reactor N2 - The effectiveness of energy conversion and carbon dioxide sequestration in Integrated Gasification Combined Cycle (IGCC) is highly dependent on the syngas composition and its further processing. Water gas shift membrane reactor (WGSMR) enables a promising way of syngas-to-hydrogen conversion with favourable carbon dioxide sequestration capabilities. This paper deals with a numerical approach to the modelling of a water gas shift reaction (WGSR) in a membrane reactor which promotes a reaction process by selectively removing hydrogen from the reaction zone through the membrane, making the reaction equilibrium shifting to the product side. Modelling of the WGSR kinetics was based on Bradford mechanism which was used to develop a code within Mathematica programming language to simulate the chemical reactions. The results were implemented as initial and boundary conditions for the tubular WGSMR model designed with Aspen Plus software to analyze the broader system behaviour. On the basis of selected boundary conditions the designed base case model predicts that 89.1% CO conversion can be achieved. Calculations show that more than 70% of carbon monoxide conversion into hydrogen appears along the first 40% of reactor length scale. For isothermal conditions more than two thirds of the heat released by WGSR should be extracted from the first 20% of the reactor length. Sensitivity analysis of the WGSMR was also performed by changing the membrane’s permeance and surface area. UR - https://www.sv-jme.eu/article/simulation-of-water-gas-shift-membrane-reactor-for-integrated-gasification-combined-cycle-plant-with-co2-capture/
@article{{sv-jme}{sv-jme.2011.100}, author = {Lotrič, A., Sekavčnik, M., Kunze, C., Spliethoff, H.}, title = {Simulation of Water-Gas Shift Membrane Reactor for Integrated Gasification Combined Cycle Plant with CO2 Capture}, journal = {Strojniški vestnik - Journal of Mechanical Engineering}, volume = {57}, number = {12}, year = {2011}, doi = {10.5545/sv-jme.2011.100}, url = {https://www.sv-jme.eu/article/simulation-of-water-gas-shift-membrane-reactor-for-integrated-gasification-combined-cycle-plant-with-co2-capture/} }
TY - JOUR AU - Lotrič, Andrej AU - Sekavčnik, Mihael AU - Kunze, Christian AU - Spliethoff, Hartmut PY - 2018/06/29 TI - Simulation of Water-Gas Shift Membrane Reactor for Integrated Gasification Combined Cycle Plant with CO2 Capture JF - Strojniški vestnik - Journal of Mechanical Engineering; Vol 57, No 12 (2011): Strojniški vestnik - Journal of Mechanical Engineering DO - 10.5545/sv-jme.2011.100 KW - IGCC, water-gas shift reaction, membrane reactor N2 - The effectiveness of energy conversion and carbon dioxide sequestration in Integrated Gasification Combined Cycle (IGCC) is highly dependent on the syngas composition and its further processing. Water gas shift membrane reactor (WGSMR) enables a promising way of syngas-to-hydrogen conversion with favourable carbon dioxide sequestration capabilities. This paper deals with a numerical approach to the modelling of a water gas shift reaction (WGSR) in a membrane reactor which promotes a reaction process by selectively removing hydrogen from the reaction zone through the membrane, making the reaction equilibrium shifting to the product side. Modelling of the WGSR kinetics was based on Bradford mechanism which was used to develop a code within Mathematica programming language to simulate the chemical reactions. The results were implemented as initial and boundary conditions for the tubular WGSMR model designed with Aspen Plus software to analyze the broader system behaviour. On the basis of selected boundary conditions the designed base case model predicts that 89.1% CO conversion can be achieved. Calculations show that more than 70% of carbon monoxide conversion into hydrogen appears along the first 40% of reactor length scale. For isothermal conditions more than two thirds of the heat released by WGSR should be extracted from the first 20% of the reactor length. Sensitivity analysis of the WGSMR was also performed by changing the membrane’s permeance and surface area. UR - https://www.sv-jme.eu/article/simulation-of-water-gas-shift-membrane-reactor-for-integrated-gasification-combined-cycle-plant-with-co2-capture/
Lotrič, Andrej, Sekavčnik, Mihael, Kunze, Christian, AND Spliethoff, Hartmut. "Simulation of Water-Gas Shift Membrane Reactor for Integrated Gasification Combined Cycle Plant with CO2 Capture" Strojniški vestnik - Journal of Mechanical Engineering [Online], Volume 57 Number 12 (29 June 2018)
Strojniški vestnik - Journal of Mechanical Engineering 57(2011)12, 911-926
© The Authors, CC-BY 4.0 Int. Change in copyright policy from 2022, Jan 1st.
The effectiveness of energy conversion and carbon dioxide sequestration in Integrated Gasification Combined Cycle (IGCC) is highly dependent on the syngas composition and its further processing. Water gas shift membrane reactor (WGSMR) enables a promising way of syngas-to-hydrogen conversion with favourable carbon dioxide sequestration capabilities. This paper deals with a numerical approach to the modelling of a water gas shift reaction (WGSR) in a membrane reactor which promotes a reaction process by selectively removing hydrogen from the reaction zone through the membrane, making the reaction equilibrium shifting to the product side. Modelling of the WGSR kinetics was based on Bradford mechanism which was used to develop a code within Mathematica programming language to simulate the chemical reactions. The results were implemented as initial and boundary conditions for the tubular WGSMR model designed with Aspen Plus software to analyze the broader system behaviour. On the basis of selected boundary conditions the designed base case model predicts that 89.1% CO conversion can be achieved. Calculations show that more than 70% of carbon monoxide conversion into hydrogen appears along the first 40% of reactor length scale. For isothermal conditions more than two thirds of the heat released by WGSR should be extracted from the first 20% of the reactor length. Sensitivity analysis of the WGSMR was also performed by changing the membrane’s permeance and surface area.